A dash of ruthenium atoms on a mesh of copper nanowires could be one step toward a revolution in harvesting ammonia from nitrates in wastewater and groundwater.
Collaborators at Rice University’s George R. Brown School of Engineering, Arizona State University and Pacific Northwest National Laboratory developed the high-performance catalyst that can, with near 100 percent efficiency, pull ammonia and solid ammonia from low levels of nitrates that are widespread in wastewater and polluted groundwater.
A study led by Rice chemical and biomolecular engineer Haotian Wang shows the process converts nitrate levels of 2,000 parts per million into ammonia, followed by an efficient gas stripping process for ammonia product collection. The remaining nitrogen contents after these treatments can be brought down to drinkable levels as defined by the World Health Organization.
“We fulfilled a complete water denitrification process,” said graduate student Feng-Yang Chen. “With further water treatment on other contaminants, we can potentially turn industrial wastewater back to drinking water.”
Chen is one of three lead authors of the paper that appears in Nature Nanotechnology.
The study shows a promising alternative toward efficient processes for the ammonia industry, which depends upon an energy-intensive process to produce more than 170 million tons of ammonia per year.
The researchers knew from previous studies that ruthenium atoms are great at catalyzing nitrate-rich wastewater. They chose to combine it with copper, which suppresses the hydrogen evolution reaction.
“We knew that ruthenium was a good metal candidate for nitrate reduction, but we also knew there was a big problem, that it could easily have a competing reaction, which is hydrogen evolution,” Chen said. “When we applied current, a lot of the electrons would just go to hydrogen, not the product we want.”
“We borrowed a concept from other fields like carbon dioxide reduction, which uses copper to suppress hydrogen evolution,” added Wang. “Then we had to find a way to organically combine ruthenium and copper. It turns out that dispersing single ruthenium atoms into the copper matrix works the best.”
The process works at room temperature, under ambient pressure and a nitrate reduction current of 1 amp per square centimeter. That should make it easy to scale up, Chen said.
“I think this has big potential, but it’s been ignored because it’s been hard for previous studies to reach such a good current density while still maintaining good product selectivity, especially under low nitrate concentrations,” he said. “But now we’re demonstrating just that. I’m confident we’ll have opportunities to push this process for industrial applications, especially because it doesn’t require big infrastructure.”
A prime benefit of the process is the reduction of carbon dioxide emissions from traditional industrial production of ammonia., which amount to 1.4 percent of the world’s annual emissions, the researchers noted.
“While we understood that converting nitrate wastes to ammonia may not be able to fully replace the existing ammonia industry in the short term, we believe this process could make significant contributions to decentralized ammonia production, especially in places with high nitrate sources,” Wang said.
